A New Lithium-Rich Anti-Spinel in Li–O–Br System
Document Type
Article
Publication Date
5-11-2015
Publication Title
Chemical Communications
Volume
51
Issue
47
First page number:
9666
Last page number:
9669
Abstract
In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an “electronically inverted” anti-spinel. The new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li5Br(OH)4 under moderate pressure and temperature conditions.
Disciplines
Astrophysics and Astronomy
File Format
File Size
1930 KB
Repository Citation
Zhang, J.,
Zhao, Y.,
Wang, L.,
Zhu, J.
(2015).
A New Lithium-Rich Anti-Spinel in Li–O–Br System.
Chemical Communications, 51(47),
9666-9669.
http://dx.doi.org/10.1039/C5CC01109D